Nanocomposite of ZnO with montmorillonite for removal of lead and copper ions from aqueous solutions

The clay minerals montmorillonite (MMT) was combined with ZnO to form efficient nanocomposite which was used as an adsorbent. Zinc oxide nanoparticles (ZnO-NP) were successfully incorporated into the layers of montmorillonite by green simple heat method using zinc nitrate and sodium alginate as zinc oxide precursor and stabilizer respectively. The XRD and FESEM measurements revealed the presence of ZnO nanoparticles with hexagonal wurtzite structure in the ZnO/MMT nanocomposites. The role of the ZnO in enhancing the adsorption efficiency of the ZnO/MMT nanocomposite for the removal of copper and lead ions from aqueous solutions was investigated. The effects of different parameters such as contact time, dosage, initial concentration, and pH were investigated. Kinetics of adsorption were studied using pseudo-first-order and pseudo-second order. The efficiency of the nanocomposites was studied by Langmuir and Freundlich isotherms. The material showed high efficiency in a wide pH range, for the adsorption of Pb and Cu ions. Kinetic studies showed that the adsorption followed the pseudo-second-order and equilibrium best described by Langmuir isotherm. The regeneration results show that the nanocomposites can be utilized for at least three times because of its stability and durability. Thus, it can serve as a promising adsorbent for the removal of copper and lead ions from aqueous solutions. (C) 2017 Institution of Chemical Engineers. Published by Elsevier B.V. All rights reserved.