期刊
DESIGNED MONOMERS AND POLYMERS
卷 21, 期 1, 页码 75-81出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/15685551.2018.1459078
关键词
Copolymers; polypyrrole; poly(o-phenylenediamine); chemical polymerization; fluorescence
资金
- DST-SERB [SB/S1-PC-070/2013]
Tailoring of conjugated monomers via copolymerization is a facile method to obtain tunable spectral, morphological and optical properties. To investigate the effect of copolymerization of pyrrole with o-phenylenediamine on the optoelectronic properties of the synthesized copolymers, the present work reports the synthesis of copolymers of o-phenylenediamine with pyrrole with varying mol ratios via chemical polymerization in methylene blue (MB) medium. Copolymerization was confirmed by Fourier transform infrared spectroscopy and ultraviolet-visible studies. Ultraviolet-visible spectroscopy revealed variation in the optical properties with the change in the monomer ratio. Fluorescence studies showed that the copolymer containing 80% poly(o-phenylenediamine) revealed highest quantum yield among all the copolymers. The emission color could therefore be tuned by careful selection of narrow band co-monomers, which could help in designing tunable fluorescence emitting materials for potential application in OLED devices.
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