Large-moment antiferromagnetic order in overdoped high-Tc superconductor 154SmFeAsO1-xDx

In iron-based superconductors, high critical temperature (T-c) superconductivity over 50 K has only been accomplished in electron-doped hREFeAsO (hRE is heavy rare earth (RE) element). Although hREFeAsO has the highest bulk T-c (58 K), progress in understanding its physical properties has been relatively slow due to difficulties in achieving high-concentration electron doping and carrying out neutron experiments. Here, we present a systematic neutron powder diffraction study of (SmFeAsO1-xDx)-Sm-154, and the discovery of a long-range antiferromagnetic ordering with x >= 0.56 (AFM2) accompanying a structural transition from tetragonal to orthorhombic. Surprisingly, the Fe magnetic moment in AFM2 reaches a magnitude of 2.73 mu(B)/Fe, which is the largest in all nondoped iron pnictides and chalcogenides. Theoretical calculations suggest that the AFM2 phase originates in kinetic frustration of the Fe-3d(xy) orbital, in which the nearest-neighbor hopping parameter becomes zero. The unique phase diagram, i.e., highest-T-c superconducting phase adjacent to the strongly correlated phase in electron-overdoped regime, yields important clues to the unconventional origins of superconductivity.