期刊
62ND DAE SOLID STATE PHYSICS SYMPOSIUM
卷 1942, 期 -, 页码 -出版社
AMER INST PHYSICS
DOI: 10.1063/1.5029141
关键词
Titanium oxide; Ruthenium oxide; Ruthenium doped titanium oxide; cyclic voltammetery; Supercapacitor
资金
- Department of Science and Technology (DST)
Ru doped TiO2 thin films are prepared by using 0.06 M aqueous solution of potassium titanium oxalate (pto), and 0.005 M aqueous solution of ruthenium tri chloride (RuCl3) precursors. The deposition was carried on stainless steel (SS) by using well known ultrasonic spray pyrolysis technique (USPT) at 723 degrees K by maintaining the spray rate 12 cc/min and compressed air flow rate 10 Lmin(-1). Prepared Ru: TiO2 thin films were characterized by structurally, morphologically and electrochemically. Deposited RuO2 shows amorphous structure and TiO2 shows tetragonal crystal structure with rutile as prominent phase at very low decomposition temperature. SEM micrographs of RuO2 exhibits porous, interconnected, spherical grains type morphology and TiO2 shows porous, nanorods and nanoplates like morphology and also Ru doped TiO2 shows porous, spherical, granular and nanorods type morphology. The electrochemical cyclic voltammetery shows mixed capacitive behavior. The achieved highest value of specific capacitance 2692 F/g was Ru doped TiO2 electrode in 0.5 M H2SO4.
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