期刊
POLYMER INTERNATIONAL
卷 66, 期 6, 页码 839-850出版社
WILEY
DOI: 10.1002/pi.5323
关键词
renewable resource; hyperbranched aliphatic polyurethane; castor oilmodified polyol; UV resistance; shape memory polymer
Renewable resource tailored tough, elastomeric, biodegradable, smart aliphatic hyperbranched polyurethanes were synthesized using castor oil modified polyol containing fatty amide triol, glycerol, diethanolamine and monoglyceride of sunflower oil via an A(x) + B-y (x, y >= 2) approach. To the best of our knowledge, this is the first report of the synthesis of solely aliphatic hyperbranched polyurethanes by employing renewable resources. The synthesized polyurethanes were characterized by Fourier transform infrared, NMR and XRD techniques. The hyperbranched polyurethanes exhibited good mechanical properties, especially elongation at break (668%), toughness (32.16 MJ m(-3)) and impact resistance (19.02 kJ m(-1)); also high thermal stability (above 300 degrees C) and good chemical resistance. Also, the hyperbranched polyurethanes were found to show adequate biodegradability and significant UV light resistance. Moreover, they demonstrated excellent multi-stimuli-driven shape recovery ability (up to 97%) under direct sunlight (105 lux), thermal energy (50 degrees C) and microwave irradiation (450 W). The performance of the hyperbranched polyurethanes was compared with renewable resource based and synthetic linear polyurethane to judge the superiority of the hyperbranched architecture. Therefore, these new aliphatic macromolecules hold significant promise as smart materials for advanced applications. (C) 2017 Society of Chemical Industry
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