期刊
ACS OMEGA
卷 3, 期 5, 页码 4908-4917出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.8b00499
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资金
- SERB, New Delhi [EMR/2016/006358]
- Indian Institute of Science
- CSIR, New Delhi [02(0226)15/EMRII]
- R.L. Fine Chem
- Synovation Chemicals and Sourcing Pvt. Limited, Bangalore
- CSIR
Metal-free chemoselective hydroamination of styrene derivatives has been achieved with high chemo-selectivity over sulfenylation of 1H-tetrazole-5-thiol using a catalytic amount of iodine. The scope of this methodology has been extended for the hydroamination of a-substituted styrene derivatives. This reaction involves a single-step C-N-bond formation under atom economical process. This eco-friendly method uses readily available and inexpensive iodine in a catalytic amount.
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