期刊
POLYMER CHEMISTRY
卷 8, 期 9, 页码 1555-1561出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6py02218a
关键词
-
资金
- National Natural Science Foundation of China [21474048, 21674046, 51673093]
Three kinds of chiral BINOL-based polymers could be synthesized by polymerization in a Pd-catalyzed cross-coupling reaction. The resulting chiral polymers can exhibit strong mirror image Cotton effects. Interestingly, only P2 and P3 can emit circularly polarized luminescence (CPL) signals, which can be attributed to the chirality transfer of the BINOL moiety via the rigid pi-conjugation chain backbone structure system. This work can develop a new strategy for the design of novel CPL materials.
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