期刊
POLYMER
卷 128, 期 -, 页码 373-378出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2017.01.038
关键词
Gel; Bilayer; Anisotropy; Swelling; Diffusion
资金
- JSPS KAKENHI [JP124225006, JP15F15043]
- Grants-in-Aid for Scientific Research [15F15043, 26820300, 17K19146] Funding Source: KAKEN
Novel, supramolecular, anisotropic hydrogels (called MC-PDGI gels) are presented in this study. These MC-PDGI gels consist of multi-cylindrical lipid bilayers aligned in a uniaxial manner and embedded in a soft hydrogel matrix. The bilayers and the hydrogel interact weakly due to hydrogen bonding. These MC-PDGI gels swell after exposure to water, which causes their volume and diameter to increase while simultaneously causing their length to decrease. This anisotropic swelling-induced contraction behavior is the result of competition between the isotropic elasticity of the hydrogel matrix and the interfacial tension of the lipid bilayers. Moreover, the MC-PDGI gels exhibit unique quasi one-dimensional diffusion behavior owing to the difficulty of molecular penetration through the multi-layered lipid bilayers. These materials would be useful for prolonged drug release or as an actuator. (C) 2017 Elsevier Ltd. All rights reserved.
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