Progress on Incorporating Zeolites in Matrimid®5218 Mixed Matrix Membranes towards Gas Separation

Membranes, as perm-selective barriers, have been widely applied for gas separation applications. Since some time ago, pure polymers have been used mainly for the preparation of membranes, considering different kinds of polymers for such preparation. At this point, polyimides (e.g., Matrimid (R) 5218) are probably one of the most considered polymers for this purpose. However, the limitation on the performance relationship of polymeric membranes has promoted their enhancement through the incorporation of different inorganic materials (e.g., zeolites) into their matrix. Therefore, the aim of this work is to provide an overview about the progress of zeolite embedding in Matrimid (R) 5218, aiming at the preparation of mixed matrix membranes for gas separation. Particular attention is paid to the relevant experimental results and current findings. Finally, we describe the prospects and future trends in the field.