期刊
ACS OMEGA
卷 3, 期 7, 页码 7587-7602出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.8b00471
关键词
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资金
- National Research Foundation of Korea (NRF)
- Ministry of Science, ICT, and Future Planning [2017R1A2B1004860]
- National Research Foundation of Korea (NRF) - Korean government [2017R1A4A1015581]
- National Research Foundation of Korea [2017R1A4A1015581] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
A zero-dimensional/two-dimensional heterostructure consists of binary SnO2-ZnO quantum dots (QDs) deposited on the surface of graphitic carbon nitride (g-C3N4) nanosheets. The so-called SnO2-ZnO QDs/g-C3N4 hybrid was successfully synthesized via an in situ co-pyrolysis approach to achieve efficient photoactivity for the degradation of pollutants and production of hydrogen (H-2) under visible-light irradiation. High-resolution transmission electron microscopy images show the close contacts between SnO2-ZnO QDs with the g-C3N4 in the ternary SnO2-ZnO QDs/g-C3N4 hybrid. The optimized hybrid shows excellent photocatalytic efficiency, achieving 99% rhodamine B dye degradation in 60 min under visible-light irradiation. The enriched charge-carrier separation and transportation in the SnO2-ZnO QDs/g-C3N4 hybrid was determined based on electrochemical impedance and photocurrent analyses. This remarkable photoactivity is ascribed to the smart heterostructure, which yields numerous benefits, such as visible-light-driven fast electron and hole transfer, due to the strong interaction between the SnO2-ZnO QDs with the g-C3N4 matrix. In addition, the SnO2-ZnO QDs/g-C3N4 hybrid demonstrated a high rate of hydrogen production (13 673.61 mu mol g(-1)), which is 1.06 and 2.27 times higher than that of the binary ZnO/g-C3N4 hybrid (12 785.54 mu mol g(-1)) and pristine g-C3N4 photocatalyst (6017.72 mu mol g(-1)). The synergistic effect of increased visible absorption and diminished recombination results in enhanced performance of the as-synthesized tin oxide-and zinc oxide-modified g-C3N4. We conclude that the present ternary SnO2-ZnO QDs/g-C3N4 hybrid is a promising electrode material for H-2 production and photoelectrochemical cells.
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