期刊
PHYSICAL REVIEW LETTERS
卷 119, 期 13, 页码 -出版社
AMER PHYSICAL SOC
DOI: 10.1103/PhysRevLett.119.136001
关键词
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资金
- European Research Council [ERC-2011-AdG-290981, ERC-2016-STG-714870]
- European Union Seventh Framework Programme [FP7-PEOPLE-2013-CIG-618229]
- Spanish MINECO [MAT2014-53432-C5-5-R]
- Maria de Maeztu program for Units of Excellence in RD [MDM-2014-0377]
The second law of photochemistry states that, in most cases, no more than one molecule is activated for an excited-state reaction for each photon absorbed by a collection of molecules. In this Letter, we demonstrate that it is possible to trigger a many-molecule reaction using only one photon by strongly coupling the molecular ensemble to a confined light mode. The collective nature of the resulting hybrid states of the system (the so-called polaritons) leads to the formation of a polaritonic supermolecule involving the degrees of freedom of all molecules, opening a reaction path on which all involved molecules undergo a chemical transformation. We theoretically investigate the system conditions for this effect to take place and be enhanced.
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