期刊
PHYSICA C-SUPERCONDUCTIVITY AND ITS APPLICATIONS
卷 534, 期 -, 页码 29-36出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.physc.2016.12.006
关键词
Iron sulfide; Iron-based superconductor; Antiferromagnetism
资金
- DOE Office of Science Graduate Student Research Program
- Oak Ridge Institute for Science and Education for the Department of Energy [DE-AC05060R23100]
- U.S. Department of Energy (DOE),
- Office of Science
- Basic Energy Sciences (BES)
- Materials Science and Engineering Division
- Chemical Sciences
- Geosciences
- Biosciences Division
- Scientific User Facilities Division
- Office of BES
- U.S. DOE
- ORNL's Lab-Directed Research & Development of the Wigner Fellowship program
- U.S. Department of Energy, Office of Basic Energy Sciences [DE-FG02-10ER46783]
For iron-sulfide (FeS), we investigate the correlation between the structural details, including its dimensionality and composition, with its magnetic and superconducting properties. We compare, theoretically and experimentally, the two-dimensional (2D) layered tetragonal (t-FeS) phase with the 3D hexagonal (h-FeS) phase. X-ray diffraction reveals iron-deficient chemical compositions of t-Fe0.93(1)S and h-Fe0.84(1)S that show no low-temperature structural transitions. First-principles calculations reveal a high sensitivity of the 2D structure to the electronic and magnetic properties, predicting marginal antiferro-magnetic instability for our compound (sulfur height of z(s) =0.252) with an ordering energy of about 11 meV/Fe, while the 3D phase is magnetically stable. Experimentally, h-Fe0.84S orders magnetically well above room temperature, while t-Fe0.93S shows coexistence of antiferromagnetism at T-N =116 and filamentary superconductivity below T-c=4 K. Low temperature neutron diffraction data reveals antiferromagnetic commensurate ordering with wave vector k(m) = (0.25,0.25,0) and 0.46(2)mu(B)/Fe. Additionally, neutron scattering measurements were used to find the particle size and iron vacancy arrangement of t-FeS and h-FeS. The structure of iron sulfide has a delicate relationship with the superconducting transition; while our sample with a=3.6772(7)angstrom is a filamentary superconductor coexisting with an antiferromagnetic phase, previously reported samples with a > 3.68 angstrom are bulk superconductors with no magnetism, and those with a approximate to 3.674 angstrom show magnetic properties.(C) 2016 Elsevier B.V. All rights reserved.
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