期刊
PHYSICA B-CONDENSED MATTER
卷 526, 期 -, 页码 84-88出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.physb.2017.09.039
关键词
Amorphous materials; Glasses; Differential Scanning Calorimetry; Raman Spectroscopy; Optical properties
资金
- SERB-DST [SB/S2/LOP-013]
- DST
Glasses in the TeO2-ZnO-BaF2 system were prepared by standard melt quenching technique and were characterized for their thermal, optical and structural properties. Samples were found to show good thermal stability with values ranging above 100 degrees C for all the compositions. Optical bandgap and refractive index values were calculated from linear optical measurements using UV-Vis spectroscopy. Infrared spectra showed the presence of hydroxyl groups in the glasses indicating that the effect of fluorine was negligible in removing the hydroxyl impurities for the experimental conditions and compositions used. Raman measurements showed the modification occurring in the glass network due to addition of barium fluoride in terms of increase in the formation of non-bridging oxygen atoms compared to strong Te-O-Te linkages in the glass matrix.
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