In situ fast pyrolysis of biomass with zeolite catalysts for bioaromatics/gasoline production: A review

The fast pyrolysis of biomass-based feedstocks is currently gaining considerable attention as an industrial and sustainable option for the production of gasoline-range bioaromatics. The complex composition of biomass molecules and a series of reactions involved during the upgrading process require the incorporation of sufficiently acidic and topological catalysts. This paper carefully documents and analyzes recent publications that have investigated the properties of zeolites to enhance the yield of bioaromatics during in situ fast pyrolysis. Issues related to the effects of zeolite's textural, topological and acidic properties are critically examined. Factors responsible for catalyst deactivation and the mechanistic roles of the catalysts used are discussed. This paper also explores the prospects of hierarchical zeolites and municipal solid waste (MSW) as catalysts and feedstocks for the fast pyrolysis process. (C) 2015 Elsevier Ltd. All rights reserved.