4.3 Article

Screening Commercial Semiconductors for Visible Light Driven Asymmetric Catalysis

期刊

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ppsc.201700280

关键词

asymmetric alkylation; heterogeneous catalysis; photocatalysis; semiconductor; visible light

资金

  1. National Key Basic Research Program of China [2014CB931801, 2016YFA0200700]
  2. National Natural Science Foundation of China [21475029, 91427302]
  3. Frontier Science Key Project of the Chinese Academy of Sciences [QYZDJ-SSW-SLH038]
  4. Instrument Developing Project of the Chinese Academy of Sciences [YZ201311]
  5. CAS-CSIRO Cooperative Research Program [GJHZ1503]
  6. Chinese Academy of Sciences [XDA09040100]
  7. K.C. Wong Education Foundation

向作者/读者索取更多资源

To find cheap and commercially available materials that are efficient in the catalytic process is of paramount importance for practical application in both chemical and biomedical engineering. As-purchased nanosized semiconductors are systematically investigated as catalysts in visible light driven asymmetric reactions with the help of chiral ligands. Significantly, among varied semiconductors, WO3 exhibits the best performance with 91% enantiomeric excess and 95% conversion ratio.

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