期刊
ORGANOMETALLICS
卷 36, 期 14, 页码 2677-2684出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.7b00290
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资金
- National Natural Science Foundation of China [21571017]
- Natural Sciences and Engineering Research Council of Canada [RGPIN 1193993-2013]
A 1,1-hydroboration reaction was used successfully to create brominated BN-heterocyclic compounds, which are amenable to Stile coupling reactions for the construction of new BN-heterocyclic compounds, including a new polymeric BN-heterocycle that has an extended pi-conjugated backbone. The conjugated backbone of the new BN-heterocydes was found to have a great influence on the photophysical and electronic properties of this class of compounds. In addition, the photoelimination reactivity of the new BN-heterocycles was also found to be greatly dependent on the extent of the conjugated backbone. Several new 1,2,4-triazole-fused boranaphthalenes have been obtained successfully via photoelimination.
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