期刊
ORGANIC PROCESS RESEARCH & DEVELOPMENT
卷 21, 期 2, 页码 247-252出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.oprd.6b00410
关键词
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资金
- Novartis
- NSF (GOALI) [SusChEM 1566212]
An operationally simple and general process for the safe and selective reduction of nitro groups utilizing ppm Pd supported on Fe nanomaterials in aqueous solution of designer surfactant TPGS-750-M has been developed and successfully carried out at a 100 mmol scale. Preferred use of KBH4 as the hydride source, at ambient temperature and pressure, lends this process suitable for a standard reaction vessel alleviating the need for specialized hydrogenation equipment. Calorimetry data parallel those expected for a classical nitro group reduction when measuring the heat of reaction (-896 to -850 kJ/mol).
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