期刊
ORGANIC PROCESS RESEARCH & DEVELOPMENT
卷 21, 期 12, 页码 2018-2024出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.oprd.7b00315
关键词
-
资金
- Natural Science Foundation of China [21403256, 21372102, 21573261]
- Suzhou Industrial Technology and Innovation Project [SYG201531]
A manganese octahedral molecular sieve (OMS-2) was found to be an efficient and recyclable heterogeneous catalyst for the oxidative synthesis of benzoxazoles in the gram-scale from phenolic imines at room temperature. H2O2 and biobased reagent dimethyl carbonate (DMC) were successfully employed as the environmentally friendly oxidant and solvent, respectively, in an OMS-2-catalysted redox reaction for the first time. Benzoxazoles could also be obtained from N-substituted 2-aminophenols via Cu(OH)(x)/OMS-2-catalyzed sequential oxidative transformation at elevated temperatures.
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