期刊
ORGANIC PROCESS RESEARCH & DEVELOPMENT
卷 21, 期 12, 页码 1925-1937出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.oprd.7b00288
关键词
-
The novel oxidant of sodium hypochlorite pentahydrate (NaOCl center dot 5H(2)O) crystals is now available for industrial and laboratory use. It is superior to conventional aqueous sodium hypochlorite solutions (aq. NaOCl). The crystalline material is 44% NaOCl and contains minimal amounts of sodium hydroxide and sodium chloride, and the aqueous solution, which is prepared from NaOCl center dot 5H(2)O and water, has a pH of 11-12. Examples of the selective organic synthesis using NaOCl center dot 5H(2)O involve the oxidations of primary and secondary alcohols, selective oxidations to sulfoxide and sulfone, oxidative cleavage of disulfide to sulfonyl chloride and bromide, oxaziridine synthesis, and oxidative dearomatization of phenols.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据