期刊
ORGANIC LETTERS
卷 19, 期 5, 页码 1080-1083出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00106
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资金
- CUNY Collaborative Research Incentive Program
- PSC-CUNY award [69069-0047]
- Seed Grant from the Office for the Advancement of Research at John Jay College, CUNY
- National Science Foundation [CHE-1464543]
- [54247-UNI3]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1464543] Funding Source: National Science Foundation
An ionic cobalt-PNP complex is developed for the efficient alpha-alkylation of ketones with primary alcohols for the first time. A broad range of ketone and alcohol substrates were employed, leading to the isolation of alkylated ketones with yields up to 98%. The method was successfully applied to the greener synthesis of quinoline derivatives while using 2-aminobenzyl alcohol as an alkylating reagent.
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