期刊
ORGANIC LETTERS
卷 19, 期 12, 页码 3159-3162出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01282
关键词
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资金
- Chinese NSF [81430080, 81373277]
- National Program on Key Basic Research Project of China [2015CB910603]
- International Cooperative Program [GJHZ1622]
- Chinese Academy of Sciences [160621]
- Shanghai Commission of Science and Technology [16XD1404600, 14431905300, 14431900400]
A novel and efficient C-H activation approach for the direct 3,3-difhioroallylation of 2-pyridones and indoles is herein reported using a manganese(I) complex as the catalyst. A broad range of substrates with diverse functional groups were tolerated. Moreover late-stage C-H functionalization of bioactive molecules was achieved in good yield.
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