期刊
ORGANIC LETTERS
卷 19, 期 3, 页码 440-443出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03399
关键词
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资金
- NSF of China [21572072]
- Science and Technology Innovation Program of the Universities of Henan Province [16HAS-TIT007]
- Zhengzhou University
An efficient and regioselective alkenylation of azaheterocycle N-oxides with alkenes catalyzed by iodine under metal- and external oxidant-free reaction conditions has been developed. A variety of (E)-2-styrylazaheterocycles have been produced in moderate to excellent yields. The mechanistic exploration indicated that the N-oxide group played dual roles as both the directing group and an internal oxidant in this catalytic cycle.
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