期刊
ORGANIC LETTERS
卷 19, 期 3, 页码 600-603出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03625
关键词
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资金
- NSFC [21472076, 21532001]
- PCSIRT [IRT_15R28, lzujbky-2016-ct02]
A new class of chiral atropoisomeric (P, N) ligand precursors has been obtained with excellent diastereoselectivities and high yields through diastereoselective metal free intramolecular radical oxidative C-H amination with chiral phosphamide as the auxiliary group. This method provides a concise and highly valuable pathway for the synthesis of enantiopure aminophosphine ligands in largescale.
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