期刊
ORGANIC LETTERS
卷 19, 期 21, 页码 5736-5739出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02488
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资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Centre in Green Chemistry and Catalysis (CGCC)
- Universite Laval
- CGCC
An efficient iron-catalyzed carbene insertion reaction of alpha-diazo carbonyl compounds into the Si-H bond was developed. A wide range of alpha-silylesters was obtained in high yields (up to 99%) from alpha-diazoesters using a simple iron(II) salt as catalyst.
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