期刊
ORGANIC LETTERS
卷 19, 期 16, 页码 4187-4190出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01712
关键词
-
资金
- National Basic Research Program of China [2015CB856500]
- Natural Science Foundation of Tianjin [16JCYBJC20100]
A general and facile synthetic method for C(sp(2))H difluoroalkylations and perfluoroalkylations of alkenes and (hetero)arenes with commercially available fluoroalkyl halides has been developed with a copper-amine catalyst system. This method is characterized by high yields, mild reaction conditions, low-cost catalyst, broad substrate scope, and excellent functional group compatibility, therefore providing a convenient synthetic strategy toward various difluoroalkyl- and perfluoroalkyl-substituted alkenes and (hetero)arenes.
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