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ORGANIC LETTERS
卷 19, 期 23, 页码 6268-6271出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02704
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资金
- NSFC [21372256, 21572264]
Palladium-catalyzed [5 + 2] cycloaddition of 2-aryl-2-vinyloxiranes with sulfamate-derived cyclic imines is described. The zwitterionic allylpalladium intermediates act as five-membered synthon to react with sulfamate-derived cyclic imines to furnish [5 + 2] cycloaddition, giving 1,3-oxazepine derivatives in moderate to excellent yields with excellent regioselectivities.
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