期刊
ORGANIC LETTERS
卷 19, 期 8, 页码 2102-2105出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00702
关键词
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资金
- NSF of China [21572072, 21602064]
- Xia-men Southern Oceanographic Center [15PYY052SF01]
- Science and Technology Bureau of Xiamen City [3502Z20150054]
- Huaqiao University
Picolinamide has first been employed as a traceless directing group for the cobalt-catalyzed oxidative annulation of benzylamides with alkynes to synthesize isoquinolines through C-H/N-H bonds activation. Oxygen is used as a terminal oxidant. This protocol exhibits good functional group tolerance and excellent regioselectivity. Both terminal and internal alkynes can be efficiently applied to this catalytic system as substrates.
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