期刊
ORGANIC LETTERS
卷 19, 期 7, 页码 1846-1849出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00610
关键词
-
资金
- NSFC [21632003, 21372105, 21572087]
- 111 program from the MOE of P. R. China
A variety of spirocyclohexene pyrazolones were synthesized in good yields with excellent stereoselectivities through an asymmetric, intermolecular, quaternary carbon center forming [3 + 3] cycloaddition reaction catalyzed by a bifunctional catalyst. The vinylogous pyrazolones used as binucleophilic synthons in this reaction exhibited: superior ability for constructing pyrazolone related spirocyclic scaffolds.
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