期刊
ORGANIC LETTERS
卷 19, 期 12, 页码 3075-3078出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01148
关键词
-
资金
- Board of Research in Nuclear Science (ERNS), Mumbai [37(2)/14/12/201S/BRNS/10549]
- CSIR
A method for the cross-coupling reactions of aryldiazonium salts with trialkylallylsilanes via merged gold/photoredox catalysis is described. The reaction is proposed to proceed through a photoredox-promoted generation of an electrophilic arylgold(III) intermediate that undergoes transmetalation with allyltrimethylsilane to form allylarenes.
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