期刊
ORGANIC LETTERS
卷 19, 期 17, 页码 4428-4431出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01873
关键词
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资金
- Deutsche Forschungsgemeinschaft
- Karl and Anna Buck Stiftung
- state of Baden-Wurttemberg through bwHPC
- German Research Foundation (DFG) [INST 40/467-1 FUGG]
The boron-nitrogen-boron (BNB) zigzag edged benzo[fg]tetracene is accessible from 4-butyl-2,6-diphenylaniline in four steps in good yields. The two mesityl groups stabilize the boron centers toward nucleophilic attack and result in two enantiomeric forms in the solid state. The title compound has a large optical gap, shows blue fluorescence, and is quite resistant toward oxidation and reduction.
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