期刊
ORGANIC LETTERS
卷 19, 期 13, 页码 3576-3579出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01518
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资金
- Universite libre de Bruxelles (ULB)
- Federation Wallonie-Bruxelles (ARC)
- COST action [CM1202]
- Fonds pour la formation a la Recherche dans l'Industrie et dans l'Agriculture (F.RI.A.)
A broadly applicable copper catalyst for photoredox transformations of organic halides is reported. Upon visible light irradiation in the presence of catalytic amounts of [DPEphos)(bcp)Cu]PF6 and an amine, a range of unactivated aryl and alkyl halides were shown to be smoothly activated through a rare Ch(I)/Cu(I)*/Cu(0) catalytic cycle. This complex efficiently catalyzes a series of radical processes, including reductions, cyclizations, and direct arylation of arenes.
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