期刊
ORGANIC LETTERS
卷 19, 期 5, 页码 1032-1035出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00010
关键词
-
资金
- National Natural Science Foundation of China [21625206, 21632009, 21372247, 21572258, 21572259, 21421002]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
A shelf-stable and easily convertible reagent for the preparation of diversified fluoroalkylthiolated compounds, [[(ethoxycarbonyl)difluoromethyl]thio]phthalimide, was developed. [[(Ethoxycarbonyl)difluoromethyl]thio]phthalimide is an efficient electrophilic fluoroallylthiolating reagent that reacted with electron-rich heteroarenes/arenes, beta-ketoesters, oxindoles, benzofuranones, and thiols. More importantly, the ethoxycarbonyl group of the resulting fluoroalkylthiolated compounds could be easily converted into various other functional groups such as chloride, alkynyl, hydrocarbonyl, carbomoyl, hydromethyl, or heteroaryl groups.
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