期刊
ORGANIC LETTERS
卷 19, 期 23, 页码 6332-6335出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03152
关键词
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资金
- MOST [2016YFA0204100]
- NSFC [21672178, 21402164]
- Thousand Youth Talents Plan
An unprecedented electrochemical aromatic C-H oxygenation reaction for the synthesis of 4H-1,3-benzoxazines from easily available N-benzylamides is reported. These oxidative cyclization reactions proceed in a transition metal-and oxidizing reagent-free fashion and produce H-2 as only theoretical byproduct. Adapting the C-H oxygenation reaction in an electrochemical microreactor has been demonstrated.
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