期刊
ORGANIC LETTERS
卷 19, 期 19, 页码 5454-5457出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02764
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资金
- Wuhan University of Technology
- Fundamental Research Funds for the Central Universities
- National Natural Science Foundation of China [21602165]
- Department of Education of Hubei Province (China)
- Hundred Talent Program of Hubei Province
- Wuhan Youth Chen-Guang Project [2016070204010113]
Triarylsulfonium, alkyl- and fluoroalkyl(diaryl)sulfonium, and aryl(dialkyl)sulfonium triflates are successfully used as a new family of cross-coupling participants in the Sonogashira reaction as aryldiazonium, diaryliodonium, and tetraphenylphosphonium salts. It was found that terminal alkynes reacted mildly with triarylsulfonium or (2,2,2-trifluoroethyl)diphenylsulfonium triflate at room temperature under Pd- and Cu-cocatalysis to give the corresponding arylalkynes in up to >99% yield. This protocol represents the first use of arylsulfonium salts as cross-coupling partners in the Pd/Cu-catalyzed Sonogashira reaction.
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