期刊
ORGANIC LETTERS
卷 19, 期 14, 页码 3751-3754出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01594
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资金
- SERB-DST [EMR/2016/001643]
- CSIR-New Delhi
- UGC-New Delhi
A hitherto unreported aminomethylation occurs at C-3 of imidazopyridines with morpholine. in the presence of (diacetoxyiodo)benzene at ambient temperature in short reaction times. This methodology is also applicable to indolizine, imidazo[2,1-b]thiazele,benzo[d]imidazo[2,1-,b]thiazole, and indole. Interestingly, the aminomethylation involving morpholine as a source of methylene group is a new phenomenon. This protocol is of much potential for the synthesis of aminomethylated derivatives under mild reaction conditions.
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