4.8 Article

Palladium- and Nickel-Catalyzed Decarbonylative C-S Coupling to Convert Thioesters to Thioethers

期刊

ORGANIC LETTERS
卷 20, 期 1, 页码 44-47

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AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03305

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资金

  1. NIH NIGMS [GM073836]
  2. Danish National Research Foundation (Carbon Dioxide Activation Center
  3. CADIAC)
  4. UM-ICIQ Global Engagement Program
  5. NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM073836] Funding Source: NIH RePORTER

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This Letter describes the development of a catalytic decarbonylative C-S coupling reaction that transforms thioesters into thioethers. Both Pd- and Ni-based catalysts are developed and applied to the construction of diaryl, aryl alkyl, and heterocycle-containing thioethers.

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