期刊
ORGANIC LETTERS
卷 19, 期 8, 页码 2098-2101出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00701
关键词
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资金
- Natural Science Foundation of China
- Shandong province [21572118, JQ201505]
- fundamental subject construction funds [104.205.2.5]
- Shandong University
Metalated triazoles are the key reactive intermediate of the current click reaction (CuAAC). Bench-stable 5-stannyl triazoles are obtained by a copper-catalyzed interrupted click reaction of easily available terminal alkynes. Subsequent palladium-catalyzed cross-coupling reactions, electrophilic trifluoromethylthiolation and trifluoromethylation, generate diverse 1,4,5-trisubstituted triazoles efficiently, which the traditional click reaction is unable to do.
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