期刊
ORGANIC LETTERS
卷 19, 期 20, 页码 5605-5608出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02721
关键词
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资金
- TIFR Centre for Interdisciplinary Science Hyderabad, Hyderabad, India
- SERB-DST, India [EMR/2014/001237]
- Department of Science and Technology, New Delhi, India
- SERB-DST [EMR/2014/000247]
Herein, the isolation and characterization of N-peralkyl-substituted NHCCAAC derived triazaalkenes in three oxidation states, neutral, radical cation, and dication, are reported. Cyclic voltammetry has shown the reversible electronic coupling between the first and second oxidation to be Delta E-1/2 = 0.50 V. As a proof-of-principle, to demonstrate the electron-rich nature of the triazaalkene, it was shown that it can be used as an electron donor in the reduction of an aryldiazonium salt to the corresponding arene.
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