期刊
ORGANIC LETTERS
卷 19, 期 5, 页码 1132-1135出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00148
关键词
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资金
- National Natural Science Foundation of China [21472134, 21172164]
- Key Laboratory of Organic Chemistry of Jiangsu Province
- Jiangsu Higher Education Institutions (PAPD)
The first iron-catalyzed esterification of the primary benzylic C-H bonds with carboxylic acids using di-tert-butyl peroxide as an oxidant is achieved by novel ionic iron(III) complexes containing an imidazolinium cation. The use of well-defined, air-stable, and available iron(III) complex in a 5 mol % loading and readily available starting materials with a broad generality and outstanding sterically hindered tolerance renders this methodology a useful alternative to other protocols that are typically employed for the synthesis of benzyl esters.
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