期刊
ORGANIC LETTERS
卷 19, 期 4, 页码 938-941出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00117
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The first direct alpha-arylation of aldehyde-derived N,N-dialkylhydrazones with electron deficient aryl and heteroaryl cyanides under visible-light photoredox catalysis has been developed. Structurally complex alpha,alpha'-diaryl-N,N-cycloalkylhy-drazones were obtained in moderate yields by repetition of the direct arylation protocol. A continuous-flow procedure for the preparation of alpha-aryl-N,N-dialkylhydrazones on a multigrarn scale has also been established.
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