期刊
ORGANIC LETTERS
卷 19, 期 5, 页码 1192-1195出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00067
关键词
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资金
- NSFC [51432001, 51372003, 51672002]
- Natural Science Foundation of Anhui Province [1308085MB24]
- Research Foundation from College of Chemistry & Chemical Engineering of Anhui University
The (KOBu)-Bu-t-mediated three-component coupling reaction of indoles, [60]fullerene, and haloalkane has been developed as a practical and efficient protocol for the one-pot synthesis of various 1,4-(3-indole)(organo)[60]fullerenes. The reaction exhibits high regioselectivity at the 3-position of indoles and the 1,4-position on the [60]fullerene core. Furthermore, this methodology features excellent functional group tolerance, such as chloro, ester, cyano, and nitro on indole.
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