期刊
ORGANIC LETTERS
卷 19, 期 8, 页码 1982-1985出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00508
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资金
- DST-SERB [EMR/2015/001759]
- IISER Mohali
An organocatalytic approach toward a-arylated nitriles using N-heterocyclic carbene (NHC) as a catalyst is described. This protocol comprises an NHC catalyzed activation of Me3Si-CN followed by 1,6-conjugate addition of cyanide to para-quinone methides (p-QMs) and fuchsones leading to alpha-diaryl- and a-triaryl nitriles in good to excellent yields.
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