期刊
ORGANIC LETTERS
卷 19, 期 21, 页码 5728-5731出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02456
关键词
-
资金
- NSFC/China [21620102006]
- State Key Laboratory of Chemical Engineering
- Fundamental Research Funds for the Central Universities
- NIH [RO1-CA215157]
Two novel discrete organoplatinum(II) metallacycles are prepared by means of coordination-driven self-assembly of a 90 degrees organoplatinum(II) acceptor, cis-(PEt3)(2)Pt-(OTf)(2), with two donors, a pyridyl donor, 9,10-di(4pyridylvinyl)anthracene, and one of two dicarboxylate ligands. Both metallacycles display aggregation -induced emission as well as solvatochromism. More interestingly, both metallacycles exhibit near -infrared fluorescent emission in the solid state and can be used to detect ammonia gas.
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