期刊
ORGANIC LETTERS
卷 19, 期 19, 页码 5264-5267出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02532
关键词
-
资金
- National Research Foundation of Korea (NRF) - Korean government (MSIP) [NRF-2015R1A5A1008958, NRF-2015R1C1A2A01053504]
A palladium-catalyzed intermolecular hydroamination of vinylarene derivatives using anilines has been developed for the first time under aerobic conditions, where the regioselective formation of N-arylketimines is accomplished. The current aerobic oxidative hydroamination pathway of anilines is distinct from that of palladium catalyzed hydroamination reactions that proceed to give sec-arylethylamine and arylethylamine derivatives, identifying a longstanding missing reaction pathway, Wacker-type amination, to N-arylketimines using anilines. The ready availability of both starting materials, vinylarenes and anilines, offers an attractive and facile synthetic route to N-arylketimines in good to excellent yields.
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