期刊
ORGANIC LETTERS
卷 19, 期 18, 页码 4762-4765出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02122
关键词
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资金
- JSPS KAKENHI [JP17H05051]
- Platform Project for Supporting Drug Discovery and Life Science Research from Japan Agency for Medical Research and Development (AMED)
- Grants-in-Aid for Scientific Research [17H05051] Funding Source: KAKEN
A transition-metal-catalyzed cyclopropanation followed by ring opening was investigated for the synthesis of octahydroquinolines 4 and decahydroquinolines 5 having a quaternary carbon center at the angular position, which are core structures of the fawcettimine-type alkaloids. A tandem reaction was also established for the synthesis of decahydroquinolines 5 and the tricyclic compound 6 through an iminium ion intermediate, readily produced by acidic treatment of cyclopropane 2.
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