期刊
ORGANIC LETTERS
卷 19, 期 12, 页码 3311-3314出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01470
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资金
- JSPS KAKENHI [JP15K18835]
- Grants-in-Aid for Scientific Research [15K01817] Funding Source: KAKEN
The synthesis and optical resolution of helically chiral 5,6,9,10-tetrahydro-1-[6]helicenethiol and its subsequent transformations to enantiopure 1-sulfur-functionalized [6]helicenes are reported. A novel enantiopure [7]thiahelicene having a thiophene ring at the terminal position of the [6]helicene skeleton was synthesized.
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