期刊
ORGANIC LETTERS
卷 19, 期 6, 页码 1294-1297出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b00089
关键词
-
资金
- National Natural Science Foundation of China [81620108027, 21632008, 21602234, 81220108025]
- Major Project of Chinese National Programs for Fundamental Research and Development [2015CB91 0304]
Herein, rhodium(III)-catalyzed C-H activation/subsequent [4 + 1] cyclization reactions between benzamides and propargyl alcohols are reported in which propargyl alcohols serve as unusual one carbon units. This title transformation led to a series of isoindolinones bearing a quaternary carbon with moderate to good yields without the requirement for external metal oxidants. Due to the mild and simple reaction conditions, this reaction is compatible with various functional groups.
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