期刊
ORGANIC LETTERS
卷 19, 期 14, 页码 3903-3906出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01797
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A convergent asymmetric total synthesis of phorbaketal,A was achieved in 10 steps through a Au(I)-catalyzed intramolecular spiroketalization reaction of an alkyne, diol intermediate prepared from (R)-catvone and geranial. The spirciketalization reaction was ratio, and stereoselective and was accompanied by isomerization of an exo-olefin into the trisubstittned olefin to form a unique spiroketal structure of phorbaketals.
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