期刊
ORGANIC LETTERS
卷 19, 期 23, 页码 6420-6423出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03307
关键词
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资金
- National Science and Engineering Research Council (NSERC) of Canada
- Canada Foundation for Innovation (CFI)
- FRQNT Centre in Green Chemistry and Catalysis (CGCC)
- Universite de Sherbrooke
- NSERC
The synthesis of a new family of iodonium zwitterions, in which the formal anion is a trifluoroborate moiety, is reported. These reagents present very good stability and have high resistance toward benzyne formation. Their structures were confirmed by X-ray crystallographic analysis and were further investigated using DFT calculations. QTAIM analysis supports an ionic, noncovalent, I+center dot center dot center dot BF3- interaction, in accordance with a true zwitterionic nature. Preliminary results of synthetic applications, the arylation of phenolates and trifluoroborate group functionalization, are reported.
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