期刊
ORGANIC LETTERS
卷 19, 期 23, 页码 6352-6355出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03194
关键词
-
资金
- CAS Interdisciplinary Innovation Team
- National Natural Science Foundation of China [21672199]
Higher pi-extended naphthalene, contained in methylnaphthalenes, which could capture alkyl radicals via SOMO-LUMO interactions, enabled the development of Cu-catalyzed formal [4 + 2] and [3 + 2] cycloadditions between methylnaphthalenes and electron-deficient alkenes. Under copper catalysis, a series of electron-deficient alkenes and methylnaphthalenes with different substituents were successfully incorporated with di-tert-butyl peroxide (TBP) as an oxidant and radical initiator, providing a wide range of cycloadducts.
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